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Darkrema is a rare Battle Arena exclusive Pokemon and was one of the first Pokemon to be made obtainable through donation. In order to obtain the Darkrema, a donation was to be made to Pokemon Battle Arena, and the Pokemon would be given as a gift in the Pokemon PC.
Darkrema appears in the Psychic map, but you can't catch him, even with Master Balls, the only way to get him is for trade or buy him in the Spend My Credits page for 50 credits, special Darkrema can only be trade and is even harder to find as by obtaining from the donation under Spend My Credits, only the normal Darkrema can be obtained.