Magma boss 4

Magma boss 4 has many Fire Pokemon and he's hard, but only because he has a Moltres who uses Sky Attack that usually goes first. A Pokemon resistant to Flying Type moves (Aggron in particular) should be able to outlast it.

After beating Magma boss 4, you get a Pokedoll from them. With a Pokedoll you can evolve:

Golbat to Crobat

Pichu to Pikachu

Cleffa to Clefairy

Igglybuff to Jigglypuff

Togepi to Togetic

Azurill to Marill

Wynaut to Wobuffet

Munchlax to Snorlax

Riolu to Lucario

Buneary to Lopunny (unconfirmed)

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